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Jute Apparel: Jute Jacket, Jute Footwear, Jute Fashion Accessories
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Here the dye contains a reactive group and this reactive group makes covalent bond with the fibre polymer and act as an integral part of fibre. This covalent bond is formed between the dye molecules and the terminal –OH (hydroxyl) group of cellulosic fibres on between the dye molecules and the terminal –NH2 (amino) group of polyamide or wool fibres.
Reaction of Reactive Dye:
Here, D= dye part.
Wool = wool polymer.
Cell = cellulosic polymer.
Reasons for so named:
Reactive dyes are so called because this is the only type of dye, which has reactive group, and that reactive group reacts chemically with fibre polymer molecules and form covalent bond. This covalent bond is formed between the reactive group and terminal –OH (Hydroxyl) group of polyamide and wool fibre or between reactive group and terminal -NH2 (Amino) group of cellulosic fibre polymer. The strength of this covalent bond is more than ionic bond, hydrogen bond and Vander Waal’s force of attraction. Thus the reactive group becomes an integral part of the fibre.
For this reasons the dyes are so called. They are also called ‘fibre reactive group’.
History of Reactive Dye:
On the occasion of 100 year’s celebration of synthetic dye manufacturing, two chemists of ICI company (UK) named Stephen and Rattee tried to manufacture a new dyestuff. Thus they succeed to invent a new dye in 16965, which was named REACTIVE DYE. This was manufacture for dyeing cellulosic fabrics. The first three reactive dyes were PROCION YELLOWR, PROCION BRILLIANT RED 2B and PROCION BLUE 3G.for this effort they were awarded gold medal of the society of dyes and colorists for the year 1960.
Which Fibers can be dyed with Reactive Dye:
By reactive dyes the following fibres can be dyed successfully:
1) Cotton, rayon, flax and other cellulosic fibres.
2) Polyamide and wool fibres.
3) Silk and acetate fibres.
It covers a wide range of color spectrum and includes shades varying from bright to heavy dark like,
a. Violet
b. Blue
c. Green
d. Red
e. Black
f. Yellow
g. Etc.
| Chemical structure of reactive dyes |
D= dye part or chromogen (color producing part)
Dyes may be direct, acid, disperse, premetallised dye etc.
G = reactive group bearing part.
Trade name | Manufacturer | Country |
Procion | I.C.I | U.K |
Ciba cron | Ciba | Switzerland |
Remazol | Hoechst | Germany |
Levafix | Bayer | Germany |
Reactone | Geigy | Switzerland |
Primazin | BASF | Germany |
Drimarine | Sandoz | Switzerland |
Reactive are mostly used for dyeing cellulosic fibres. At past cellulosic fibres were dyed with direct and vat dyes, but after the introduction of reactive dyes there utility has become limited. Reactive dyes are superior to direct dye in the following aspects:
i) Ability to procedure bright shades of wide range.
ii) High leveling quality.
iii) Good washing fastness.
iv) Good light fastness.
And it is superior to vat dyes in the following aspects:
i) Simple dyeing method therefore one stage dyeing.
ii) Low temperature dyeing (below 1000C)
iii) Lower cost, i.e. cheaper.
Again its dyeing process is fast and gives brighter shades than metallized azo dyes. For the above reasons reactive dyes are more popular.
Properties of Reactive Dye:
1) Reactive dyes are cationic dyes, which are used for dyeing cellulose, protein and polyamide fibres.
2) Reactive dyes are found in power, liquid and print paste form.
3) During dyeing the reactive group of this dye forms covalent bond with fibre polymer and becomes an integral parts of the fibre.
4) Reactive dyes are soluble in water.
5) They have very good light fastness with rating about 6. The dyes have very stable electron arrangement and can protect the degrading effect of ultra-violet ray.
6) Textile materials dyed with reactive dyes have very good wash fastness with rating about 4-5 due to strong covalent bonds formed between fibre polymer and reactive group of dye.
7) Reactive dye gives brighter shades and has moderate rubbing fastness.
8) Dyeing method of reactive dyes is easy. It requires less time and low temperature for dyeing.
9) Reactive dyes are comparatively cheap
10)Reactive dyes have good perspiration fastness with rating 4-5. Reactive dyes have good perspiration fastness.
· Triazine group
· Pyridimine group
· Quinoxaline dyes
Example:
Triazine derivatives: procion, cibacron.
Pyridimine derivatives: reactone
Quinoxaline derivatives: levafix.
b) Activated vinyl compound:
· Vinyl sulphone
· Vinyl acrylamide
· Vinyl sulphonamide.
Vinyl sulphone: remazol
Vinyl acrylamide: primazine
Vinyl sulphonamide: levafix.
2) On the basis of reactivity:
a) Lower reactive dye:
Here ph is maintained 12-12.5 by using NaOH in bath.
b) Medium reactive dye: here pH is maintained 11-12 by using Na2CO3 in dye bath.
c) Higher reactive dye: here pH is maintained 10-11 by using NaHCO3 in dye bath.
a) Cold brand:
These types of dyes contain reactive group of high reactivity. So dyeing can be done in lower temperature i.e. 320-600C.
For example: PROCION M, LIVAFIX E.
b) Medium brand:
This type of dyes contains reactive groups of moderate reactivity. So dyeing is done in higher temperature than that of cold brand dyes i.e. in between 600-710C temperatures.
For example, Remazol, Livafix are medium brand dyes.
c) Hot brand:
This type of dye contains reactive groups of least reactivity. So high temperature is required for dyeing i.e. 720-930 C temperature is required for dyeing.
For example PRICION H, CIBACRON are hot brand dyes.
Now they are mentioned below:
1. Dye absorption:
When fibre is immersed in dye liquor, an electrolyte is added to assist the exhaustion of dye. Here NaCl is used as the electrolyte. This electrolyte neutralize the negative charge formed in the fibre surface and puts extra energy to increase dye absorption. So when the textile material is introduces to dye liquor the dye is exhausted on to the fibre.

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| Dyeing Curve |
At first fabric, required water and required anti creasing agent is added in the dye bath. Then sequestering agent and gluber salt of required amount is added in the dye bath. Then the bath is kept rest for 5 minutes. After that reactive dye of required amount is added in the dye bath. After adding dye in the dye bath, the bath is kept for 30 minutes. During this period exhaustion of dye occurs in the fabric. Then required amount of alkali is added for fixation of dye into the fabric. After adding alkali we will wait for 50 minutes and then we will check the shade. If shade is all right then fabric will be taken for after treatment.
After Treatment of Reactive Dye:
